Dr. Prof. Chanjuan Xi
Tel:86-10-62782695
Email:cjxi@tsinghua.edu.cn
EDUCATION:
1982.08 - 1986.07B. Sci. Department of Chemistry, Lanzhou University, China
1991.04 - 1994.05M Sci. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, China
1996.04 - 1999.03Ph.D. Graduate School of Pharmaceutical Sciences, Hokkaido University, Japan
EXPERIENCES:
1986.07-1995.08Assistant Professor, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, China
1995.11-1996.03Researcher, Catalysis Research Center, Hokkaido University, Japan
2000.05-2005.12 Associate Professor, Department ofChemistry, TsinghuaUniversity, Beijing
2006.01 – presentProfessor, Department of Chemistry, TsinghuaUniversity, Beijing
COURSES:
Physical Organic Chemistry
Organic Chemistry
Elementary Organic Chemistry
Advanced Organic Chemistry
RESEARCH INTERESTS:
Development of synthetic chemistry based on organometallic compounds:
1) Development of novel reaction for organic synthesis using organometallic compounds
2) Synthesis, structure and characterization of organometallic compounds
CURRENT RESEARCH:
1) Development of novel reaction for the synthesis of cyclic compounds
2) Development of novel reaction for the synthesis of functionalized ester
3) Development of Novel reaction for the synthesis of special materials
RECENT PUBLISHES:
1Xianghua Yang, Chanjuan Xi, Yanfeng Jiang, Regioselective nitration of N,N-dialkylanilines using cerium(IV) ammonium nitrate in acetonitrile, Tetrahedron Lett., 2005, 46, 8781-8783.
2Yanfeng Jiang, Chanjuan Xi, Xianghua Yang, CuBr/H2O2 - Mediated Oxidative Coupling of N,N-Dialkylarylamines in Water: A Practical Synthesis of Benzidine Derivatives, Synlett. 2005, 1381-1384.
3Chanjuan Xi, Yanfeng Jiang, Xianghua Yang, Remarkably Efficient Oxidative Coupling of N,N-Dialkylarylamines in Water Mediated by Cerium(IV) Ammonium Nitrate, Tetrahedron Lett. 2005, 46, 3909-3911.
4Chao Chen, Chanjuan Xi, Yanfeng Jiang, Xiaoyin Hong, 1,1-Cycloaddition of Oxalya Dichloride with Dialkenylmetal Compounds: Formation of Cyclopentadienone Derivatives by the Reaction of 1,4-Dilithio-1,3-dienes or Zirconacyclopentadienes with Oxalyl Chloride in the Presence of CuCl, J. Am. Chem. Soc., 2005, 127, 8024-8025.
5Yanfeng Jiang, Chanjuan Xi, Yuzhou Liu, Juan Niclós-Gutiérrez, Duane Choquesillo-Lazarte, Intra-molecular “CH/π(Metal Chelate Ring) Interactions” as Structural Evidence for Metalloaromaticity in Bis(pyridine-2,6-diimine)Ru(II) Complexes, Eur. J. Inorg. Chem., 2005, 1585-1588.
6Chao Chen, Chanjuan Xi, Yongling Shi, Xiaoyin Hong, A One-pot Multicomponent Reaction for theStereocontrolled Synthesis of Allyl-substituted Cyclopropanes, Synlett. 2005, 911-914.
7Chanjuan Xi, Chao Chen, Jie Lin, and Xiaoyin Hong, Pd-Catalyzed One-Pot Multicomponent Coupling Reaction for the Highly Regioselective Synthesis of Polysubstituted Benzenes,Org. Lett., 2005, 7, 347-349.
8Chunbo Lai, Chanjuan Xi, Yanfeng Jiang and Ruimao Hua, One-pot approach for the regioselective synthesis of β-keto sulfones based on acid-catalyzed reaction of sulfonyl chlorides with arylacetylenes and water, Tetrahedron Lett., 2005, 46, 513-515.
9Chanjuan Xi, Chunbo Lai, Chao Chen, Ruji Wang, Acid-promoted Reaction of Sulfonyl Chlorides with Alkenes: New Approach to the Regioselective Synthesis of β-Hydroxyl Sulfone Derivatives, Synlett. 2004, 1595-1597.
10Chao Chen Chanjuan Xi, Yanfeng Jiang, Xiaoyin Hong, Michael Addition Reaction of Grignard Reagents to 2-Halogenoacrylates: A Convenient Method for the Synthesis of Polysubstituted Cyclopropane Compounds, Tetrahedron Lett., 2004, 45, 6067-6069.
11Chao Chen, Chanjuan Xi, Chunbo Lai, Ruji Wang, Xiaoyin Hong, Coupling Reaction of 1,4-Dicopper-1,3-dienes: Formation of Carbocycles, Eur. J. Org. Chem., 2004, 647-650.
12Lian Leng, Chanjuan Xi, Chao Chen, Chunbo Lai, Effect of lithium chloride on allylation of zirconacyclopentadienes, Tetrahedron Lett., 2004, 45, 595-598.
13Chunbo Lai, Chanjuan Xi, Chao Chen, Mingming Ma, Xiaoyin Hong, Metallo-Phosphorylation of Alkynes: Reaction of Alkynes with Cp2Zr(1-butene)(PR3) and Chlorophosphate, Chem. Comm., 2003, 2736-2737.
14Lian Leng, Chanjuan Xi, Yongling Shi, Baohua Guo, Dianionic Cycloaddition of Decatetraenes with RCOX Forming Nine-membered Carbocycles, Synlett. 2003, 183-186.
15Chanjuan Xi, Mingming Ma, Xiaodong Li, Metallo-Phosphorylation of Olefins: Reaction of Diethyl Chlorophosphate with Zirconcene-Ethylene Complex, Chem. Comm.2001, 2554-2555.